Redox Reactions and Titration

IMPORTANT

Redox Reactions and Titration: Overview

This topic consists of various concepts like Redox Reactions as a Basis for Titrations,,, etc.

Important Questions on Redox Reactions and Titration

HARD
IMPORTANT

Given below are two statements:
Statement I: In redox titration, the indicators used are sensitive to change in pH of the solution.
Statement II: In acid-base titration, the indicators used are sensitive to change in oxidation potential.

In the light of the above statements, choose the most appropriate answer from the options given below

MEDIUM
IMPORTANT

Describe the experiment to determine the effect of temperature on the rate of reaction between potassium persulphate and potassium iodide. What is the conclusion drawn from the experiment?

HARD
IMPORTANT

How many ml of 0.125 M Cr3+ must be reacted with 12.00 ml of 0.200 M MnO4- if the redox products are Cr2O72-and Mn2+?

MEDIUM
IMPORTANT

3.5 g of a mixture of NaOH and KOH were dissolved and made up to 250 ml. 25 mL of this solution were completely neutralized by 17 mL of (N/2) HCl solution. The percentage of KOH in mixture is:

MEDIUM
IMPORTANT

Which compound decolourises iodine solution?

MEDIUM
IMPORTANT

Consider the redox reaction 2S2O32-+I2S4O62-+2I-:

HARD
IMPORTANT

5 mLof 8 N nitric acid, 4.8 mL of 5 N hydrochloric acid and a certain volume of 17 M sulphuric acid are mixed together and made up to 2 L. 30 mL of this acid mixture exactly neutralise 42.9 mL of sodium carbonate solution containing one gram of Na2CO3.10H2O in 100 mL of water. Calculate the amount in grams of the sulphate ions in solution. Report the answer after multiplying with 10 and round off to the nearest integer.

MEDIUM
IMPORTANT

Phenolphthalein does not act as an indicator for the titration between:

MEDIUM
IMPORTANT

10 mL of H2O2 solution on treatment with KI and titration of liberated I2, required 10 mL of 1N hypo. Thus H2O2 is -

HARD
IMPORTANT

Acidified KMnO4 oxidises oxalic acid to CO2. What is the volume (in litres) of 10-4M KMnO4 required to completely oxidise 0.5 L of 10-2 M oxalic acid in acid medium?

MEDIUM
IMPORTANT

Amount of oxalic acid present in a solution can be determined by its titration with KMnO4 solution in the presence of H2SO4. The titration given unsatisfactory result when carried out in the presence of HCl because HCl

MEDIUM
IMPORTANT

The oxidation state of chromium in the final product formed by the reaction between KI and acidified potassium dichromate solution is

HARD
IMPORTANT

A mixture of FeO and Fe2O3 is completely reacted with 100 mL of 0.25 M acidified KMnO4 solution. The resultant solution was then titrated with zinc dust which converted Fe3+ of the solution to Fe2+. The Fe2+ required 1000 mL of 0.1 M K2Cr2O7 solution. Find out the percentage weight of Fe2O3 in the mixture.

EASY
IMPORTANT

Iodine oxidises S2O32- ion to

HARD
IMPORTANT

1.2 g of a salt with its empirical formula KxHy(C2O4)z was dissolved in 50 mL of water and its 10 mL portion required 11 mL of a 0.1 M HCl solution to reach the equivalence point. In a separate titration, 15 mL of the stock solution required 20 mL 0.2475 M KOH to reach the equivalence point. Determine the empirical formula of salt.